fairly old looking (~1980s) 4700uF 50V electrolytic. It looked to be made of moist kraft paper (i.e., the brown untreated stuff they make paper bags out of, but the thickness and strength of tissue paper) and two sheets of ~5mil aluminum (one grayer than the other, probably because it was the anode).
etc., but if they use generally the same thickness for all voltages, you'll see essentially constant CV over a series.
I think that aluminum caps pay a big volumetric penalty for the carrier foil thickness as compared to the aluminum oxide, the real dielectric. So a thicker AlO2 layer shifts the tradeoff towards more dielectric, less aluminum overhead.
For some reason, for a given C, higher voltage caps have lower ESR. I guess they just have more surface area.
John