If I may be so rude as to be practical, note that, for a given series and can size, electrolytic caps of various voltages have close to constant CV product and about the same price. But energy goes as C*V^2, so if you want to store more energy per volume and buck, buy higher voltage caps. ESR losses will be lower, too.
Film caps tend to follow the same pattern. If anything, constant CV gets cheaper with voltage.
I recently did a board with 64 relays on it. The board we're replacing had the option to order latching or non-latching relays, and we figured we could make it a dipswitch option instead. That requires us to bang all the latching relays to the off position *after* power fails. Turns out it's better to use the highest voltage supply available to pump the energy storage caps, and switch down, than to use lower voltage caps.
John