There are several brands out there, and they all work on the same principle. A continuous high voltage pulse is delivered to the water , and anything, including frogs and fish gets stunned. Unfortunately, this often eventually kills the fish,a fact not advertised in the sales brochures, altho enough research has been done to show the effects.
The units are large, and carried on a large back-pack, battery powered or small gas engines.And in each hand, the operator carries a long pole with a paddle on the submerged end, and slowly walks thru the water,stunning all life between the paddles. Largest fish are effected most.
At least one manufacturer claims to use a complicated pulse shape that doesn't permanently injure the fish, but one thing is certain; this is illegal except for research, and it isn't fun watching the results.