Odd, no one has mentioned the obvious: Bite the bullet, and go for 8 layer, The layers will be thinner, less chewed up and board's operation will be generally quieter. You should breeze through EMC testing and today 8 layer is not that much more, not really.
1 SIG1 & COMP 8 mil FR4 2 GND 10 mil prepreg 3 SIG2 8 mil FR4 4 VCC 10?? mil prepreg 5 GND 8 mil FR4 6 SIG3 10 mil prepreg 7 GND 8 mil FR4 8 SIG4 & Misc Bypassthat way smaller trace widths on the outside layers can give controlled Zo, being 3 layers, GND plane itself has lower impedance Vcc & GND are close together to gain advantage of 'free' capacitance If you need it, even SIG2 and SIG3 layers can yield fairly well controlled Zo
Ok, Ok, Can't addd the extra layer? Can you go to 32 mil total ? use 6 mil FR4 leftover prepreg as below:
if not:and MUST be 62 mil total:
1 SIG1 & COMP 12 mil FR4 2 SIG2 [+ necessary GNDs] 13 mil prepreg 3 GND 12 mil FR4 4 VCC 13 mil prepreg 5 SIG3 [+ necessary GNDs] 12 mil FR4 6 SIG4 & MiscWon't be as quiet for EMC but will make connections give controlled Zo on the surfaces, and probably work.
But I NEVER recommend separating VCC and GND planes because that often becomes a true EMC nightmare later.
It's bad enough that the vias chew holes in the planes, so striplines instead of being zero emanations, are more like 14 dB below the same level of radiation signal as a microstrip, on the surface!
If this is a short run, or you're likely to make version 2, I'd recommend going for 8 layers, the overall costs amortized can be less total Cost of layers versus layout time versus 'fussing' at the EMC Test lab etc.etc.