Most of te semiconductor houses now have online or downloadable circuit cimulators and tools. For switch mode power supplies Linear technology is a well known suplier and they have a LT switcher tool. so may as well start there.
The key to all switchmode is sizing the inductor for correct value at full current load (current de-magnetizes the coil, saturation effets) and then sizing the capacitors to limit ripple. The rest is finese. You wil also nee a good supply of schottky diodes tha also handle peakswitch mode currents.
If you need help for a commmecial product let me now and our group will put together a professinal supply and source the materials you neeed along with manufatring acument.
IN any event have fun and good luck
Marc