I have some rubber components that need protection. Previously these rubber parts deteriorated probably due to crap in the air (all I can figure since that is all the were exposed to over years of sitting untouched). These components are used for light blocking like on a camera lens and have no mechanical interfaces other than mounting.
So would using pure silicone spray be best or what? Spray and wipe off excess leaving a very think film or would it soak in?
I would not be so sure about your analysis. I have some instruments with rubber feet that have turned into a sticky gooey yucky semi-liquid mess. The problem is that out of 4 feet, only one has deteriorated. It was something in the environment, why didn't it attack only one rubber foot? I've seen similar situations with rubber idlers on tape and VCR recorders. Some of these have never seen the light of day, much less a UV lamp. My success with coating the rubber with something that blocks UV has been dismal. I use clear acrylic (Krylon) for this purpose to prevent deterioration of vinyl tape on outdoor antenna installations. It works just fine for this purpose, but not for protecting rubber. My conclusion is that UV has nothing to do with the rubber deterioration.
Another example is an Alienware (now Dell) laptop with a spray painted rubberized cover. The entire rubberized area is becoming sticky and will soon turn to goo. This includes areas which are NOT exposed to UV. If it were chemicals delivered from the users hands, it would be localized to areas of contact. That's not the situation as the entire surface is turning to goo. However, it might be an aromatic delivery mechanism.
Also note that when rubber turns to sticky goo, it does so over the entire volume of the rubber part and not just on the surface. If it were a chemical or optical attack, it would start at the surface, and be largely unaffected towards the interior. This is not the case, which leads me to suspect that it is NOT caused by an external attack.
I don't know exactly what causes the problem. My best guess(tm) is that the problem is in the manufacture of the rubber parts and paints. There seems to be a time delay involved, where everything is fine until some reaction occurs, causing instant self-destruction. Near as I can tell, what happens is that the rubber breaks cross links and returns to the petroleum based primordial tar from which it was originally derived.
This article: suggests that plastic and rubber continuously deteriorates. The deterioration can be accelerated by multiple sources.
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Jeff Liebermann jeffl@cruzio.com
150 Felker St #D http://www.LearnByDestroying.com
Santa Cruz CA 95060 http://802.11junk.com
Skype: JeffLiebermann AE6KS 831-336-2558
What's the group's experience with Armor All? Seems to help non-porous surfaces, but I'd like something that would help with the foam stuff that lines instrument cases.
That foam stuff isn't rubber, and it generally takes a long time (at least a decade) to deteriorate.
Being porous, the foam's surface area is huge. You'd have to soak the foam in the protectant! The protectant would wind up coating the equipment.
If there were some chemical that absorbed "bad chemicals" that promoted the deterioration, it could be put within the case, in a porous bag.
I have several Pelican cases for photo and electronic equipment. They're about 10 years old, and the foam shows no sign of deterioration. If it does start disintegrating, I'll be able to buy a replacement insert (probably).
The fact is that very few 'rubber' items are actually made from the sap of the rubber tree (Hevea brasiliensis). Rather, you are probably dealing with synthetic rubber, i.e. a flexible plastic. Natural rubber itself deteriorates from exposure to UV and to air. Stabilizers are incorporated into both natural and synthetic rubbers to increase durability. Depending on the stabilizers used, 'rubber' items will either get brittle or gummy when they age.
Spraying with a silicone compound won't help. The best you can do is remanufacture the part from a silicone based material.
Don't be too sure. Yes rubber get attacked by smog or other air pollutants.
Yes rubber and plastic does deteriorate / break down over time based on the chemicals used in the formulation. Some plastics turn hard and brittle, some turn to goo. The steering wheel on my truck goos out now. The plastic connectors on the engine wiring harness are now brittle and break easily.
As far as one out of four feet, well that can be totally based on something else. If that bad foot is near a fan circulating air the its environment is totally different than the other three. Other possibilities abound. Is that foot near some other device that makes it slightly warmer than the others, etc etc. Envirnomental problems.
Just saying it is difficult to blame on only one thing.
Chemically there are two Armour All products. The cleaner is a solvent that will attack stuff and I would never use it. This based on car magazines of a decade or so ago. The stuff that goes on the tires seems less problematic and might be helpful. Best as I can remember.
The foam is porous. Spray with Armor all and you'll end up with a soggy wet sponge.
You can inject air bubbles into almost anything and create a foam like material. Polyurethane, Polyethylene, Silicon, Styrene, Neoprene, etc are common materials. Offhand, I suspect that silicon or fluorosilicone foam or sponge are the most chemically resistant and oxidation tolerant. Something like this:
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Jeff Liebermann jeffl@cruzio.com
150 Felker St #D http://www.LearnByDestroying.com
Santa Cruz CA 95060 http://802.11junk.com
Skype: JeffLiebermann AE6KS 831-336-2558
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