What causes white plastic cases to yellow?

Jun 24, 2008 4 Replies

Greetings,



I would appreciate a discussion on what environmental factors cause white plastic equipment cases (which thermoplastics are used I don't know) to yellow to a sickening hue. I have a number of devices that only in one room of the house have suffered this fate over the last several years in storage. Some have been in boxes and others in the open. The room is darkened with no solar illumination and only occasionally are CFL lights used. One device only yellowed on the surface facing the ceiling. There is no smoking in the house and very little (only occasional) fry-pan cooking at a low temperature.



What chemistry is involved here? Could carpet composition or fire-retardant treating do this?



Michael


I've always assumed it was a surface oxidation process or from airbourne acids. It can often be cut back with oven cleaner but any legends etc are lost doing that. White paint goes yellow, paper goes brown in a reaction with airbourne acids.

perhaps try sci.chem

-- Diverse Devices, Southampton, England electronic hints and repair briefs , schematics/manuals list on

formatting link

There are two or three causes. Firstly, UV light can cause 'color centers' to form, kind of like the purple tint that develops in desert glass. Secondly, polymers are developed from unstable (monomer) ingredients, and there are complex aging characteristics, which cause the plastics to shrink, embrittle, or change color.

Dirt, also, may bond to the surface; if normal household cleaners (soap, Windex, Formula 409 etc.) don't work, it might be useful to apply a mild abrasive (toothpaste or metal polish).

Unusual cleaners including waterless hand cleaner, denatured alcohol (for fingerprints on keyboards), dilute lye (for smokestains), vinegar (for some mineral dusts) have proven effective. Isopropyl alcohol is NOT recommended for translucent or transparent plastics.

this was discussed recently elsewhere, lots on the subject:

formatting link

HTH

Dirt, also, may bond to the surface; if normal household cleaners (soap, Windex, Formula 409 etc.) don't work, it might be useful to apply a mild abrasive (toothpaste or metal polish).

Novus, too.

Join the Discussion

Have something to add? Share your thoughts — no account required.

Didn't find your answer?

Ask the community — no account required