Thermal runaway in a night light???
Well, some phosphors are very cheap stuff. I don't know how much they use in these LEDs, but in my applications a pound of it will last for tens of thousands of probes (.02 gram each.) Of course, they don't sell for 10 cents a piece. But cripes, it's not expensive.
Combustion synthesis began to be used in the late 1980's, I think. The method is cheap (ammonium nitrate oxidizer and urea or glycine fuels) and produces well-crystallized, very fine particle sizes very rapidly and often without the necessity of very high temps in a separate step (meaning above say 1500C) needed for annealing; or other expensive steps like mechanical separation (grinding, milling, etc., which also have the downside of often quenching the effect in the product.) It's a mature, production process producing a cheap, uniform product so far as I know.
Well, this is why I started asking in the first place. I'm just sitting here flummoxed about the idea of a weak night light LED phosphor getting completely destroyed by a few 3 eV photons over its occasional use in a 3 month time. Every aspect of that tells me something is wrong with the claim. The photon energies just don't cut it. The low intensities just don't cut it. The short calendar time just doesn't cut it. The complete loss of function doesn't make any sense, either. And rare-earth phosphors are about as stable as a piece of ceramic tile. They don't have _any_ H2O in them -- their formation temperatures make darned sure that isn't the case. And I have to buy the whole idea when there are so many reasons why it shouldn't be able to happen?
I'm not saying it can't. Like everyone else, I live a tiny life span in a small, narrow part of the world and I do not have comprehensive experience. Something could certainly surprise me. So that's why I was asking about it. I'd really like to know exactly _what_ the phosphor is. Then I could go over to the books on my shelves and take a look, at least, to see if that makes sense in this context.
I guess it's like telling me that sometimes a rock falls upwards. I might believe it, if I knew what kind of exact rock it was. (Filled with a hydrogen gas??) But I'd sure have a hard time buying it if someone didn't spend a little time describing the rock.
Hehe. I have had similar, unexplained behaviors in really good quality Burr-Brown chips. The ACF2101, for example. I would sit and monitor the integrator output for weeks at a time. It would sit wonderfully at one charge level for many minutes, then suddenly shift to a figure 3 times higher and stay there for another 5 or 10 minutes, then suddenly shift to a third value different from the other two, and then cycle around these three places. I was using a stock demo board from Burr-Brown in these tests, which was pretty well designed and made up in effect a faraday cage for it, too. One of the weird things was that the stepped levels were at discrete places. No level in between was every hit. It was as though there were a few stable places where the bias current could sit and that it would randomly jump from place to place and just sit there for a while. Then move again. The time between jumps appeared to be rather Gaussian in distribution, too. (One of the things I looked at and why I ran this for a few weeks.)
But that has nothing to do with the phosphors. I completely accept the idea that some manufacturers don't care at all and will cheat anywhere they can get away with it, even if only for a few months at a stretch. That's definitely believable. But phosphors are pretty stable from my modest experiences and I'm still struggling with all of the combined factors of the claim on that web site. I'll believe it, but I'll need to know what the phosphor is. I'm really curious about that aspect.
Jon