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s nHi Jon, I just set this up quickly on the corner of my lab bench. I stuck the capacitor into a white protoboard, attached a 1 G ohm resistor to one leg and measured the voltage from the other side of the resistor to the opposite side of the capacitor with my 10 Meg ohm input impedance voltmeter. This gave me a 1/100 voltage reading and discharged the cap at only a 10-20 nA rate. I applied 20 (something) volts to the cap for a few seconds and then recorded the voltage at different times
Time Voltage (mV)
2:26 213 2:31 202 2:44 195 3:00 190 4:00 1858:36 AM 156 (So this was the next morning 16 hours later)
I then read the heat idea and taped a 100 ohm aluminum housed power resistor to the top of the cap, tapped a thermal couple to the side, stuck some melamine foam around the outside and top. I also placed a book on top of the foam to try and hold the contraption together. (I don't want you to think this was some precision measurement.) I applied some power to the resistor,
Time Voltage(mV) Temp
10:25 150 54C 11:18 137 61C 11:29 136 61C (I then cranked up the temperature a bit more) 11:40 128 93C 11:45 120 95C 11:52 110 98C Something is beginning to stink I reduced power 12:00 100 95C Heat off, removed the foam. 12:11 98 25C End of the experimentThere was a bit of noise in the measurements as you might expect with the 1G ohm source driving the voltmeter. As I got near it to make a measurement the voltage would jump and then settle back.
The good news is that at room temperature the caps hold their charge for a long time.
George H.