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Since you know the x-axis represents time and the graph is "voltage vs time", then the y-axis is-----ta dah---voltage. I am not familiar with Winscope, but if you have graticules on the screen (lines depicting divisions of the x- and y- axes) and you know the settings of your time and voltage controls, you can compute the time and voltage over any given distance. Most scopes have a control for the y-axis that is labeled volts/division. If this were set to 1, each y-axis division would indicate 1 volt of amplitude. Works the same for time on the x-axis. Use the major divisions - sometimes these have minor divisions, usually 5 per graticule, to help you interpolate if the waveform edge doesn't fall exactly on a major line.
There is also the issue of the baseline to consider. Zero volts may not be where you think it is.
Try Googling for some basic information on oscilloscope operation so you can learn what all the usual controls do, then read the documentation that came with Winscope(?) to see what any unusual controls do.
Hope this helps.
Richard