Those Vishay Bulk Metal resistors:
are made of a proprietary variant of 75Ni-20Cr-3Al, which is roughly an order of magnitude better than Shunt Manganin, and is the lowest resistance tempco material known in the vicinity of room temperature. One commercially available variant is known as Evanohm IIRC, available as foil and wire in case you want to make your own resistors :-).
When comparing tempcos of different materials it is important also to compare the specified temperature range or better yet look at the resistance vs temp curve.
Low resistance TC metal alloys get their low TC the same way Invar gets its low thermal expansion. Invar, at one specific temperature, exactly cancels thermal expansion with a gradual phase change to a lower volume phase. Low TC resistance alloys like Manganin and NiCrAl exactly cancel tempco at one specific temperature with a gradual phase change to a lower resistance phase. The further you get from the temperature which is exactly compensated the worse the tempco in either case. Specify TC very close to the compensated temp and you can make it arbitrarily low :-).
Regards, Glen