On Fri, 22 Jan 2016 17:31:15 -0500, "Carl Ijames" Gave us:
"Heat quicker" doesn't matter. Cast iron in the oven and Al in the oven still come up together because the heat the oven makes gets infused evenly across the entire mass, and the dwell of the solder process itself is longer. Al is good for moving thermal energy, but not retaining it uniformly through a mass. The cast iron is better because it RETAINS the heat more uniformly better. He could get creative by cutting the apron form the skillet and leaving the bottom plate and perhaps a 3/8 inch side apron (1cm or so).
The oven is a good idea because it would heat from the top as well as the bottom. He could thermal epoxy the thermocouple to the skillet plate or even drill a hole in it from the side and insert the TC all the way into the hole. Placing one more in the air above the PCB assembly will likely yield what temp the PCB has been brought to/near.