Let's say you need a >10 microfarad bipolar cap rated to stand off 10 volts, right away, and and all you have in your junk box is a 50 microfarad monopolar aluminum electrolytic rated to stand off 50 volts.
If you connect the cap, backwards, to a DC supply and limit the current into the cap to something which won't blow it up, the current into the cap will eventually fall close to zero as the plates reform.