Yup, put a small voltage on one winding, and see if you get a much larger voltage on another. If so, you can tell which is the H and which is the low voltage one. Once you have identified the high and low voltage windings, you can put them in series to determine which way the phasing goes. If you get, say 50 V out of each of two windings, and then put them in series and get zero, you have them phased backwards. Reverse one winding, and you should get 100 V.
Jon