It is easy. Check it both ways. It should show 120v from hot to neutral on one side and 120 from hot to neutral on the other side. This will let you know that your hot and neutral is working. You can also measure hot to hot and you should have 240v. A 240v circuit is really 2 120 circuits in 2 different phases so there is potential between them. Not sure if phase is the correct term here, but gets the same idea.
The breaker can be tripped and appear to be closed. You should open and close breakers to be sure.
Mike