When testing a high impedance board (up to 1 G ohm) I found that the SMD 0805 10 Meg ohm resistors measured only 6 meg ohm. The problem was traced back to the liquid flux used with Rohs solder. (100 Meg and 1 G resistors are through hole and measured correctly.)
I then wanted to measure the resistance of different =91flux blobs=92. I made big solder blobs on 0805 SMD pads (spacing between pads was about
0.030 inches) I used a Keithely 610B electrometer to measure the resistances. Resistance was first measured with the flux left in place and then the board was cleaned with isopropyl alcohol (or hot water and detergent for the one water soluble flux) and measured again. The solders tested were all from Kester.#44 rosin core (the old standard) #245 low residue rosin core #48 Sn/Ag/Cu (Rohs) rosin core #331 water soluble flux
All the rosin based solders had resistances in the 3 - 7 x10^11 ohms range before cleaning. The 245 was a bit lower than the other two, (about 1/2 the resistance), but this was a =91one of=92 test and I may have just had a bit more or less flux left in place.
The 331 had 3 Meg Ohm of resistance before washing. After cleaning the 331 resistance went up to 5x10^11 ohms the same as the others. I left the rosin flux on over the weekend and found no real change. (The average resistance changed with the day (Humidity?) but they all tracked together.
On Tuesday I cleaned the rosin flux off the boards, all the boards then had about the same resistance. (#44 and #48 showed no change with cleaning, the #245 went up in resistance a bit.)
I also tried a humidity test on the boards by breathing on them. The rosin fluxed boards went down by about a factor of 2 or so. (A bit hard to determine because I found that I could also =91spray=92 charge onto the boards.) The water based flux went down by more the 90%.
Today, (at the suggestion of Grant on SED), I =91burned=92 some 44 flux with a soldering gun. I made lots of black icky stuff. The resistance was 3X10^11 ohms the same as all the other boards. (It=92s a humid day here in Buffalo.) Interestingly the 331 today has a resistance of only 0.4 X 10^11. Apparently there is some film left on the board by the water soluble fluxes and this makes it a humidity sensor. (As I think John L. has said.)
I have one question before finishing. The technician who will be soldering the first production boards complained that the Rohs solder and rosin flux (#48) is ugly looking and one gets big globs of soldered with out his beloved liquid flux. Are there any rosin based products to help? I do have an old jar of rosin at home. Is there anything that is easier to dispense onto a SMD PCB? Or some other =91tricks of the trade=92 when working with Rohs solder/ rosin flux and surface mount parts?
George H.