Just as Jack Mormons are untempleworthy and aircraft can be unairworthy, a PC is unbenchworthy when used as a source or a demodulator of audio for test and measurement purposes.
For one thing, the drives and power and reset buttons are on the front whereas the sound card, usually the I/O in this application, is either a PCI card in the back or on the motherboard.
The input and output are by a couple of sub-mini phono jacks.
This alone makes it unbenchworthy. But these problems can be addressed by DIY measures. The fact is that others, however, cannot.
The PC has a low-priced, noisy switchmode supply and a usually total lack of RF shielding internally. While not audible, the noise level can and will be induced in cabling to the DUT, the DUT itself, and everywhere else.
The PC soundcard is an entertainment grade, AC-coupled, single ended affair. PCI cards with more sophisticated, instrument grade design do exist-however they are often quite expensive. Serious cards designed for legit T&M work, usually CompactPCI, PXI, or VME/VXI, are astonishingly expensive. As are their host backplanes, enclosures, and CPU cards (although old VMEbus stuff can usually be found and the appropriate software compiled for the OS you wind up running.)
There are PC PCI oscilloscopes, spectrum analyzers, and arbs which provide their own shielded and filtered micro-environment, but not only they no cheaper than a standalone piece of test equipment, the host PC still has all of the above disadvantages.
In short, PC-based test sucks for hobbyists, technicians, and educators. It's probably OK for ATE installations, usually they go with the aforementioned PXI or VXI for good measure and inflate the budget anyway.