A customer of mine has a problem with a PCB potted in polyurethane. The circuit consists of some inputs (clamped & filtered), a microcontroller with internal RAM / flash and some power electronics to switch loads (up to 40V). 10 PCBs where produced and tested. All worked fine. 4 of those PCBs where potted and they started to show erratic behaviour like RAM corruption, software hang-ups. I already milled one of the modules to expose the microcontroller to check whether it is hot, but it stays cold. So its not a heat problem.
The polyurethane used is non-conductive and shouldn't shrink, the potting was done by a company that specializes in potting electronics; they know about ESD precautions.
Any ideas where to start looking?