Here's a piece of copperclad with a bit of 3 mil Kapton tape stuck to it,
ftp://jjlarkin.lmi.net/Cool1.JPG
(no, my hand's not that short and pudgy... that's just the angle)
and here's the same scene in the thermal IR:
ftp://jjlarkin.lmi.net/Cool2.jpg
The copper is a near-perfect mirror at these wavelengths, so you can see the reflection of my hand. But the kapton is almost black, so it ignores my hand and displays the actual temperature of the copper.
The ceiling is warmer than my desk, which explains the rest.
Neat: Kapton is also OK in ultra-high vacuum.
John