kelvin, You didn't say what processor you are trying to do this with, but the answer is, probably not.
Standar UARTs have an asynchronus receive, and an asynchronus transmit, and maybe a few handshaking signals. SPR requires a SYNCHRONOUS clock, transmit, and receive, as well as a chip select signal. They are very different beasts. If you have spare pins, you can bit-bang an SPI in software easier than try to manipulate the UARTs pins to emulate an SPI port.
Charlie