I don't understand why you need to ask this when Phil has already answered why 600v caps fail on 240V AC.
I can assist you with repeating the relevant passage here:
"A given 600 or 1000V DC rated cap may well be series wound, impregnated with oil or just use unusually thick film and so last quite well. But the vast majority of DC rated caps last only a short time when used with a 240V supply - then typically explode violently. Failure is due to internal corona discharge across trapped air pockets inside the cap eating away the insulation.
Corona simply does not occur in wound film capacitors at 100VAC, that is why I mentioned the number."
What part of this don't you understand or accept as an answer to your question?