Polymers differ between manufacturers. The Panasonics look great. I deliberately abused a bunch of them (over voltage, reverse voltage, alternate +-) and they were fine. No failures in production gear so far.
Their leakage curve is such that series stacks are self-equalizing.
56uF, 25V Panasonics, run at -10V for a month or so:I tested them up to +116 volts, the limit of my old HP bench supply, with no failures.
Measured ESR was nice and low, just right for the output of a switcher.
For low voltage switchers, 3.3 or less, hi-k ceramics work fine. But they lose C fast as voltage goes up, so polymers can take over.
Tantalums can explode from excess peak current (C * dV/dT) so are dangerous across supply rails, unless greatly voltage derated.