Thought I'd zener some NPN b-e junctions. The mode is to use the collector and emitter, base open, putting a zenered e-b junction in series with the forward-biased c-b junction, "reference zener" style.
BFT25 gives only 3.02 volts at 1 mA, with about 0.6 of that being c-b drop.
BFS17 is 3.78, 0.53 of that c-b drop.
Those are RF transistors.
A more conventional BCX70 is 8.08 volts at 1 mA, 0.608 of that c-b, and has a positive overall tc. The voltage is creeping up slowly, which may be thermal. I'll watch it for a few days and see if there's a longterm trend. Presumably I'm wrecking the beta, but I'm not testing for that.
John