Although not marketed as a transformer, most common-mode chokes can give 10 KV isolation, provided that you coat or pot them in suitable material, incl uding the connection pins where the solder to the PCB. Be sure to give ade quate creepage/clearance on your board, or solder wires made from HV insula ted wire, and mount them off the PCB. This will NOT be safety agency appro ved however, so it's not for use in anything that's AC Mains connected, or in Medical equipment.
In a similar line of practice, you can take a pair of well insulated curren t transformers that are encased in potting and include a thick plastic shel l. If lay them end to end, and loop 10-20 turns of wire through their pick
-up holes, then short the wire ends, you'll have created your own transform er. Even better is to insert some layers of insulated sleeve/tubing (into the holes), which is safety agency approved for the voltage you need to wit hstand.
If you don't need tight magnetic coupling (i.e. Some air gap is ok), then how about two off-the-shelf rod inductors laying side by side, separated by some suitable thickness of approved insulation material in between?
A final suggestion is to contact MPS Industries, in Gardena California. Th ey can provide design assistance, and they actually love to do small produc tion runs and/or prototype builds.
Regards, Terry Moreau