Strange battery

Jun 22, 2006 2 Replies

Good day.



Last week I came across one of those emergency light power supplies, the type with a 6 volt lead battery inside that are constantly hooked to a charger.



I took it home and plugged it in after attaching the battery (6v 7Ah). The yellow charge light came on. I left it for several days. Today I took the battery out. I measured the voltage. It read -3.x volts (lets say -4 volts). I had the common lead on the meter connected to the black post (clearly marked negative) and I had the other lead connected to the red post on the battery (also clearly labeled positive). I tried again.



-3.x volts. As if I had the meter connected backwards. "This isn't right" I thought. Impossible. Something is backwards here"



I took my meter and tested the voltage across a battery I knew was good, a



12v 7Ah I had been using for years. Red to red, black to black I read +12 volts or so. No problem with polarity.

BAck to the 6v battery and I see -3.x volts. I place a 6v lightbulb across the battery leads. It lights up. Not bright, but there is current flowing.



I check the charger. The dark wire (blue) connects to the circuit board at a spot clearly marked - bat. The red wire connects to the board at a spot marked +bat. I connect the red wire to the red post of the battery. The blue wire to the black post. Just like I did when I got the thing home last week.



Turned on the charger. I read -1.85 volts across the battery terminals. When the battery charger is removed the voltage reads -3.3 volts but slowly climbs to -3.7 volts (within 2 minutes).



What the hey is going on??? Is this battery shot? If so, can someone explain the chemistry going on? It is like I have not only drained the battery, but actually drained it past the 0.0 volt level and taken it into a state where a reverse reaction is going on.



Anyone?


At least one cell of the battery has been discharged too far and polarity-flipped.

Yes.

That's a reasonable (though highly simplified) explanation of what has happened - The battery has flipped polarity due to having been drawn down too far before being recharged. Not *REALLY* common, but a known issue, particularly with NiCd batteries.

As to describing the chemistry, it's beyond my own understanding/education, and therefore outside of my ability to explain.

Suffice it to say that you're not seeing anything new - It's not common, but it is a well-known failure mode of most rechargable battery types when subjected to heavy/prolonged discharge, with NiCds being the most commonly seen "victims".

Don Bruder - dakidd@sonic.net - If your "From:" address isn\'t on my whitelist, or the subject of the message doesn\'t contain the exact text "PopperAndShadow" somewhere, any message sent to this address will go in the garbage without my ever knowing it arrived. Sorry... for more info

Thanks for the reply. I'll take your word that the battery is dead. I still wonder about the chemistry though. One day I'll figure it out.

Thanks again.

Waz

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