When I was a boy in the 40s there were crystal set kits where the rectifier was the contact between a blued steel razor blade and the point of a safety pin. It helped to move the point of the pin over the razor blade to search for the best spot.
Rectifiers don't have to be perfect to give you some demodulation. Any junction with a kink in its transfer function is probably a candidate.
Reg
Heid the baw - goal!! wrote: