I think this was answered in the Xilinx forums, but basically the GC pin has dedicated routing to global resources (BUFGMUX, DCM, PLL) and the CC pin has dedicated routing to local resources (BUFR, BUFIO). A GC_CC pin would therefore have both capabilities. In the older series where local clocking resources first showed up (Spartan 3E, 3A?) there was no advantage to the local clocking if you already had the global connections. In the newer parts, the local clocking can run faster than the max toggle rate of the global routes, so there is some advantage to adding the CC capability to a GC pin.
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