People have been doing that sort of sampling for 25-30 years--first using coplanar transmission line on an electrooptic crystal like LiNbO3, where you look at the polarization shift in the light, and somewhat later using the plasma-optical effect, which can be either an optical-readout sampler or a switch. Dan Grischkowsky and Jean-Marc Halbout were doing it when I joined IBM, and before that, Dave Bloom was doing it at Stanford (he might have started it at Bell, I forget).
Using a femtosecond laser (a Hall-Haensch comb generator) will get you unmatched stability, but of course the experiment has to be synched to the laser rather than the other way round.
Telecom modulators are getting up above 50 GHz bandwidth, but only in the 1.5 um band, which is too long for GaAs.
Cheers
Phil Hobbs