Inspired by your attempt I managed to breakdown the C-B junction. Used a MPSH-10 Rf transistor on the hunch it has thin base and low breakdown voltage. Full experiment is as follows:
Device beta at start 131
- Pease style breakdown Veb, Vcb into 11meg DMM, Icb into short Ibreakdown Vcb Icb
Device beta after several mins Veb avalanche 61
- Herold/Hobbs breakdown Vcb, Veb into 11meg DMM, Ieb into short I breakdown Veb Ieb
Device beta after 1-2mins Vcb breakdown 61
Despite the MPSH10 30V Vcb rating it took nearly 80V to breakdown.
The obvious difference was the in C-B breakdown case there was no opposite sign emf at the other junction, possibly just a very slight leakage at nA levels.
If the explanation is photo-electric then it looks like the C-B breakdown does not emit light or that no photo detection takes place in the E-B junction. I got the feeling that during the Veb breakdown the MPSH10 was producing a heftier output (-540mV) than the jelly-bean device I tried in the past (300-400mV) perhaps the thin-base is a big factor.
When I next get some time for bench messing around I'll try Phil's suggestion of trying various temperatures.
piglet