The rest of the pins are probably not connected to anything, but are there for physical support.
Your digits aren't arranged for multiplexing. Displays which are arranged for multiplexing have only one group of 7 bits to control all of the digits, and separate anodes or cathodes for each of the digits. You set up the data for a digit, then turn it on using the separate anode or cathode. If you do this fast enough, it looks like they are all on.
For your device, there are several ways to go. You could use a chip designed to drive a common cathode LED for each digit. Then, you would have only 13 bits to control from the PIC, since the high bit is only a
1 or blank.The easiest way, however, is to go get some serial-in parallel out shift registers. The one I generally use for PICs is the MC14094, which have enables, strobes, and can be chained together. You have 28 bits to control, so you'll need 4 of them. (they have 8 outputs each)
There are 3 PIC pins used to shift data into the things and display it. You set a data bit either high or low, and then twiddle (0-1-0) a clock bit to clock it in. Once the bits are all shifted into the devices, you strobe the data in the shift register to the outputs using a separate strobe bit.
The clock and strobe pin from the PIC are attached to all of the shift registers. The data is attached to only the first one. There is a 'shift out' pin on the shift registers that you attach to the next one in line, etc.
I would devote a shift register to each digit, just to simplify the setup. Having a table mapping binary data to 7 segment codes simplifies matters.
Finally, you can easily get your timing data off of the AC line, if your clock is meant to be plugged in. It is a nice way to go, since it varies only a small amount, so your clock is more accurate. If you use the internal oscillator, it can easily vary by a few percent in either direction, which will cause your clock to run fast or slow. You can compensate for this a bit, but temperature also affects the oscillator in the pic, so the only really good solution is an external oscillator or crystal.