A total nonstarter as far as I can tell.
Discounting the primary problem for ALL programmers (H-1B predation and consequent employer spoilage) there is absolutely no market for General Purpose PostScript Programmers. I have never seen an ad for one yet. I have never seen this skill set even mentioned in any advertisement for Programmers in my life.
Considering that PostScript is a derivative of Forth, you would consider there would be some crossover there. Unfortunately, there is no substantial demand for Forthwrights either. It's true some basement hacker types really like Forth for embedded development. Unfortunately, most of them have to flip burgers, work at Walmart, or deal in surplus electrojunk for a living. I have enough esoteric hobbies as it is.
The other problem is the lack of toolsets and working environments for writing PostScript. GNU Ghostscript works on Unix environments, I'm told. But again that's a pretty obscure place to have to work. Using a laser printer as a computer and throwing away the output, though utterly stupid on a colossal scale, can be done. Even that is becoming tougher as the old battleaxe printers die and become unreplaceable. The last bastion for true Adobe PostScript is on some enterprise level (read: as big as an old Xerox office copier, in fact, that's what many primarily are) printers having to exist in mixed Windows/Unix environments. (Since 95% of code is actually generated on laptops today-the reason they make laptops with bizarre RISC architectures that are dead on the desktop-carrying a 500 lb printer in your notebook bag seems a bizarre requirement.)
Unix, Unix, Unix. I hate Unix, you say. Where else is PostScript used? Well, nowhere. Microsoft doesn't particularly love PostScript, Adobe being Mussolini to Steve Jobs' Apple which is, you know, that guy Godwin was bitching about.
If you are a aficionado of learning obscure and pedantic languages PostScript is up there with IBM mainframe JCL, TeX, and some of the bizarrer alternatives to perl or Python. But since human beings do not think in reverse Polish or postfix notation (maybe Poles do, but that's why they are perhaps the butts of more jokes than any other nationality on earth) it's probably safe to say that PostScript might be a fine page description language for Unix workgroup printing, but the beginner would be best directed to learn C++, perl or Java.