Use an LM2594 or whatever in that series. They're very easy to use, and list recommended parts values.
You can get negative voltages from a buck by using a multi-winding inductor. This makes +/-5V or 12, or +12/-6V (get -5 using an LDO?) very simple. Preferably use a synchronous converter like TPS54233, or put a minimum load on the main output, otherwise the negative rail won't start up.
The negative winding is phased so that it looks like a flyback supply, but it's not actually freewheeling, it's just the buck's diode-clamping phase. This is why you get a ratio to the main output voltage. (The opposite phase is supply dependent, and has forward converter action, so you'd need a choke input filter anyway.)
Afraid I don't have a drawing or appnote handy, but I think I've seen such examples in LT datasheets. LT parts are fine too, you're just paying more for them...
Tim
Seven Transistor Labs, LLC Electrical Engineering Consultation and Contract Design Website:
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Hi all, Well I get to do a SMPS. There are boat loads of IC's out there and I'm looking for recommendations. (I better go re read AoE3) I need a number of output voltages. +15V, +5V, -5V, -15V. and +24V. maximum current of 0.5A on any one. My current plan is to run the whole thing from a 24V wall wart or brick. Price and size is not too much of an issue, I guess fewer external parts would be nice... Say with the switching transistor inside the IC.
TIA George H.