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I presume this is one of those wheel around big guys seen at repair shops and service stations.
I take it that the 200 amp is a feature you can select to start vehicles if you are in a big hurry and can't wait for the original battery to accept an adequate charge.
The 6 volt battery will, for a time, swamp the 14-16 volt charging voltage output down to the 7 or 8 volts if you hook it up as is. Better if you have a trickle charge or lower charging current feature selection to buy yourself more time with the 12 volt charging hook up.
You could then actuate the 200 amp feature to see if you can start the problematic vehicle. But I wouldn't leave it on for long.
Older chargers used selenium rectifier stacks and they have a built in current limiting (intrinsic resistance) and are very conservatively built.
Charging batteries is hazardous even with the right equipment, but unless this is a very tiny ampere hour battery, you should be able to do it for a minute or two before you start heating up the plates and permanently destroying the battery and possibly the rest of the automotive electrical system.
The suggestion about adding another 6 volt battery in series would work as well, you would have to position it between the vehicle being charged and hook up the positive of the vehicle battery to the negative pole of this added battery. The positive of the added battery going to the potitive lead of the charger.
Joe Rooney