Hello folks,
this may be slightly off-topic in this group, but I know that there are enough gurus around here that can help me with this problem.
We're doing a STM spectroscopy measurement (molecules adsorbed on a substrate) and obtain the local density of states by measuring the differential conductance as a function of applied voltage using a lock-in amplifier.
For those that aren't interested in physics: we're measuring the I(V) characteristics of a black box that has two wires sticking out of it.
Applying this technique to a theoretical system that exhibits a perfect step function characteristic (i.e., something that doesn't conduct at all below a certain voltage and has uniform conduction above it) would result in a peak which naturally is broadened by the fact that the modulation voltage is finite. It's easy to see that the width of the base of the peak equals the p-p amplitude of the modulation signal.
Using a 10mV(eff) modulation voltage we cannot expect to see any features in our differential conduction function that exhibit a peak width of more than about 25-30 mV.
But we do. We see a 3mV FWHM peak above the molecules at zero bias.
From the way I understand lock-in, this is theoretically impossible. Maybe my reasoning is flawed, or we're dealing with some kind of strange artefact. The lock-in is a SR830 digital unit; we're currently trying to reproduce the experiment with an analog lock-in which is a bit difficult due to the poorer input filtering capabilities.
Another lab in our group has seen the same effect on an all-metal sample as well. At modulation frequencies of a few hundred Hz we exclude any dynamic effects, that is to say, we assume the I(V) function of the tip-sample system under investigation to be time-invariant.
Thanks for any suggestions,
--Daniel